Question
Explain cross Cannizzaro reaction with example.###Write the reaction for the action of $50 \%$ NaOH on a mixture of formaldehyde and benzaldehyde.

Answer

The reaction between two different aldehydes, not having a-hydrogen atoms is called cross Cannizzaro reaction. These two aldehydes undergo disproportionation in presence of concentrated alkali to give four products. However, if one of the aldehydes is formaldehyde, the reaction yields exclusively formate and alcohol to corresponding aldehyde.

Formaldehyde and benzaldehyde since do not have a-hydrogen atom, will undergo Cannizzaro (redox) reactions.

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