Question
Explain the addition of hydrogen halides to alkynes using a general reaction.

Answer

i. Hydrogen halides (HCl, HBr and HI) add to alkynes across carbon-carbon triple bond in two steps to form geminal dihalides (in which two halogen atoms are attached to the same carbon atom).
ii. The addition of HX in both the steps takes place according to Markovnikov’s rule as shown in below.
General reaction:
Image
iii. The order of reactivity of hydrogen halides is HI > HBr > HCl.

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