Question
Explain the following: (i) Markownikov's Law (ii) Peroxide effect
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Answer
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→$\text{MnO}^{-}_4+\text{SO}^{2-}_3+\text{H}^+\xrightarrow{ \ \ \ \ \ \ \ \ \ }\text{Mn}^{2+}+\text{SO}^{2-}_4+\text{H}_2\text{O}$
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$\text{CH}_3\stackrel{\oplus \ \ \ }{\text{CH}}_2,\text{C}_6\text{H}_5-\stackrel{\oplus\ \ \ \ }{\text{CH}}_2,(\text{CH}_3)_3\stackrel{\oplus \ \ \ \ }{\text{CH}},$
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$\text{HC}\equiv\text{C}^{\ominus},\text{Ch}_2=\stackrel{\ominus\ \ \ \ \ \ }{\text{CH}_2},\text{CH}_3-\stackrel{\ominus\ \ \ \ \ }{\text{CH}_2},\stackrel{\ominus \ \ \ \ \ }{\text{CH}_3}$ (increasing order of stabillity)
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$\text{C}_6\text{H}_5\stackrel{\bf. \ \ \ \ }{\text{CHCH}_3},\text{C}_6\text{H}_5\text{CH}_2\stackrel{\bf.\ \ \ \ \ }{\text{CH}_2},\text{C}_6\text{H}_5\stackrel{\bf.}{\text{C}}_3(\text{CH}_3)_2$ (increasing order of stabillity)
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$\text{CH}_3-\stackrel{\oplus \ \ \ \ }{\text{CH}}-\text{O}-\text{CH}_3,\text{CH}_3-\stackrel{\oplus \ \ \ \ }{\text{CH}},-\text{OCH}_3,$
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