Question
Explain the following term with suitable examples:
Frenkel defect.

Answer

Frenkel defect:It is a type of vacancy defect. In ionic compounds, some of the ions (usually smaller in size) get dislocated from their original site and create defect. This defect is known as Frenkel Defects. Since this defect arises because of dislocation of ions, thus it is also known as Dislocation Defects. As there are a number of cations and anions (which remain equal even because of defect); the density of the substance does not increase or decrease.
Ionic compounds; having large difference in the size between their cations and anions; show Frenkel Defects, such as ZnS, AgCl, AgBr, AgI, etc. These compounds have smaller size of cations compared to anions.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

Which one of the following electrolytes is the most effective for the coagulation of $Fe(OH)_3$ sol and why$?NaCl,\ Na_2SO_4,\ Na_3PO_4$
Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?
Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
The $C - Cl$ bond length in chlorobenzene is less than the $C - Cl$ bond length in $C _2 H _5 Cl$, why?
When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?
Explain the terms polymer and monomer.
Answer the following question:
Draw the structure of a noble gas species which is isostructural with $\text{BrO}^-_3.$
Why are cimetidine and ranitidine better antacids than sodium hydrogencarbonate or magnesium or aluminium hydroxide?
For a reaction
$2\text{H}_2\text{O}_2\frac{\text{I}^-}{\text{alkaline medium}}2\text{H}_2\text{O}+\text{O}_2$
the proposed mechanism is as given below:
  1. $\text{H}_2\text{O}_2+\text{I}^{-}\xrightarrow{\ \ \ \ \ \ \ }\text{H}_2\text{O}+\text{IO}^{-}(\text{slow})$
  2. $\text{H}_2\text{O}_2+\text{IO}^{-}\xrightarrow{\ \ \ \ \ \ \ }\text{H}_2\text{O}+\text{I}^{-}+\text{O}_2(\text{fast})$
  1. Write rate law for the reaction.
  2. Write the overall order of reaction.
  3. Out of steps (1) and (2), which one is rate determining step?