MCQ
For a sample of perfect gas when its pressure is changed isothermally from $p_i$ to $p_f$, the entropy change is given by
  • A
    $\Delta S = nRT\,\ln \left( {\frac{{{p_f}}}{{{p_i}}}} \right)$
  • B
    $\Delta S = RT\,\ln \left( {\frac{{{p_i}}}{{{p_f}}}} \right)$
  • C
    $\Delta S = nR\,\ln \left( {\frac{{{p_f}}}{{{p_i}}}} \right)$
  • $\Delta S = nR\,\ln \left( {\frac{{{p_i}}}{{{p_f}}}} \right)$

Answer

Correct option: D.
$\Delta S = nR\,\ln \left( {\frac{{{p_i}}}{{{p_f}}}} \right)$
d
$\Delta \mathrm{S}=\mathrm{nC}_{\mathrm{pm}} \ell \mathrm{n} \frac{\mathrm{T}_{\mathrm{f}}}{\mathrm{T}_{\mathrm{i}}}+\mathrm{nR} \ell \mathrm{n} \frac{\mathrm{P}_{\mathrm{i}}}{\mathrm{P}_{\mathrm{f}}}$

For isothermal $\mathrm{T}_{\mathrm{i}}=\mathrm{T}_{\mathrm{f}}, \ln 1=0$

$\Delta \mathrm{S}=\mathrm{nR} \ell \mathrm{n} \frac{\mathrm{P}_{\mathrm{i}}}{\mathrm{P}_{\mathrm{f}}}$

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