MCQ
For independent process at $300\,K$.

Process $\Delta H / kJ\,mol ^{-1}$ $\Delta S / J K^{-1}$
$A$ $-25$ $-80$
$B$ $-22$ $40$
$C$ $25$ $-50$
$D$ $22$ $20$

The number of non-spontaneous process from the following is $.....$

  • A
    $4$
  • B
    $6$
  • C
    $2$
  • D
    $8$

Answer

c\
$\Delta G =\Delta H - T \Delta S$

$A : \Delta G \left( J\,mol ^{-1}\right)=-25 \times 10^3+80 \times 300:- ve$

$B : \Delta G \left( J\,mol ^{-1}\right)=-22 \times 10^3-40 \times 300:- ve$

$C : \Delta G \left( J\,mol ^{-1}\right)=25 \times 10^3+300 \times 50:+ ve$

$D : \Delta G \left( J\,mol ^{-1}\right)=22 \times 10^3-20 \times 300:+ ve$

Processes $C$ and $D$ are non-spontaneous.

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