It is \(\alpha \) - subtitution when a carboxylic acid having \(\alpha \) - hydrogens is treated with chlorine or bromine in presence of small amount of red phosphorous.
\(R-C{{H}_{2}}COOH\,+\,{{X}_{2}}\,\xrightarrow{P}\) \(\begin{matrix}
X\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
RCH-COOH+HX \\
\end{matrix}\) \((X\,=\,Cl,\,Br)\)
ઉપરોક્ત પ્રકિયામાં અસંમિતકેન્દ્ર ઉદભવે છે.તો મળતો એસિડ નીચેનામાંથી કેવો હશે ?
${C_2}{H_5}I\xrightarrow{{alc. KOH}}X\xrightarrow[{CC{l_4}}]{{B{r_2}}}Y\,\xrightarrow{{KCN}}Z\xrightarrow{{{H_3}{O^ + }}}A$