Gabriel phthalimide synthesis is an example of
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- 1The correct order of basicities of the following compounds isView Solution
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$\mathop {C{H_3} - C{H_2} - N{H_2}}\limits_{\mathop 2\limits } \,$$\,\mathop {{{(C{H_3})}_2}NH}\limits_{\mathop 3\limits } $
$\mathop {C{H_3} - \mathop {\mathop C\limits^{||} }\limits^O - N{H_2}}\limits_4 $
- 2Aniline reacts with mixed acid $($conc. $HNO _3$ and conc. $H _2 SO _4 )$ at $288 K$ to give $P (51 \%)$,$Q (47 \%)$ and $R (2 \%)$. The major product$(s)$ of the following reaction sequence is $($are$)$View Solution
$\text { 1) } Ac _2 O \text {, pyridine } \text { 1) } Sn / HCl $
$R \xrightarrow{2) Br _2, CH _3 CO _2 H } S \xrightarrow{2) Br _2 / H _2 O \text { (excess) }} \text { major product(s) }$
$\text { 3) } H _3 O ^{+} \text {3) } NaNO _2, HCl / 273-278 K$
$\text { 4) } NaNO _2, HCl / 273-278 K \quad \text { 4) } H _3 PO _2$
$\text { 5) } EtOH , \Delta$ - 3In the above reactions, product $A$ and product $B$ respectively are :View Solution
- 4Assertion :Nitrobenzene is used as a solvent in Friedel-Craft's reaction.View Solution
Reason : Fusion of nitrobenzene with solid $KOH$ gives a low yield of a mixture of $o-$ and $p-$ nitrophenols - 5View SolutionWhich of the following reacts with hinsberg reagent to give product which is soluble in alkali
- 6The reaction:View Solution
$ArN _{2} Cl \overset{Cu / HCl}{\rightarrow} ArCl + N _{2}$ is known as
- 7The end product $(B)$ containing nitrogenView Solution
- 8View SolutionEthyl amine on acetylation gives
- 9Aniline when treated with conc. $HN{O_3}$ givesView Solution
- 10Phenol $+$ Aniline $\xrightarrow[{KOH}]{{{C_6}{H_5}N_2^ + C{l^ - }}}$ Major Product $:$ Product will be $:$View Solution