MCQ
Haloform reaction is characteristic of
  • Carbonyl compound having$\begin{array}{*{20}{c}}
    {O\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
    {||\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
    { - C - C{H_3}}
    \end{array}$ group
  • B
    Compound having $\begin{array}{*{20}{c}}
    {\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
    {\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
    { - C - Cl}
    \end{array}$ group
  • C
    $\begin{array}{*{20}{c}}
    O\\
    {||}\\
    {C{H_3} - C - N{H_2}}
    \end{array}$
  • D
    Anhydride

Answer

Correct option: A.
Carbonyl compound having$\begin{array}{*{20}{c}}
{O\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{ - C - C{H_3}}
\end{array}$ group
a

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$1.$ Among the following, identify the correct statement.

$(A)$ Chloride ion is oxidized by $\mathrm{O}_2$

$(B)$ $\mathrm{Fe}^{2+}$ is oxidized by iodine

$(C)$ Iodide ion is oxidized by chlorine

$(D)$ $\mathrm{Mn}^{2+}$ is oxidized by chlorine

$2.$ While $\mathrm{Fe}^{3+}$ is stable, $\mathrm{Mn}^{3+}$ is not stable in acid solution because

$(A)$ $\mathrm{O}_2$ oxidises $\mathrm{Mn}^{2+}$ to $\mathrm{Mn}^{3+}$

$(B)$ $\mathrm{O}_2$ oxidises both $\mathrm{Mn}^{2+}$ and $\mathrm{Fe}^{2+}$ to $\mathrm{Fe}^{3+}$

$(C)$ $\mathrm{Fe}^{3+}$ oxidizes $\mathrm{H}_2 \mathrm{O}$ to $\mathrm{O}_2$

$(D)$ $\mathrm{Mn}^{3+}$ oxidises $\mathrm{H}_2 \mathrm{O}$ to $\mathrm{O}_2$

$3.$ Sodium fusion extract, obtained from aniline, on treatment with iron $(II)$ sulphate and $\mathrm{H}_2 \mathrm{SO}_4$ in presence of air gives a Prussian blue precipitate. The blue colour is due to the formation of

$(A)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$ $(B)$ $\mathrm{Fe}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$

$(C)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$ $(D)$ $\mathrm{Fe}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$

Give the answer question $1,2$ and $3.$