Maharashtra BoardEnglish MediumSTD 12 ScienceChemistryAldehydes, Ketones and Carboxylic Acids3 Marks
Question
How are following compounds prepared using Gngnard reagent (1) Acetone (2) Benzophenone?
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Answer
(1) Acetone: Acetoniti-ile (ethanenitrile) reacts with methyl magnesium iodide in presence of dry ether to give imine complex which on hydrolysis gives acctonc. During reaction acetonitrile and methyl magnesium iodide should be taken in equimolecular proportion.
(2) Benzophenone: Benzonitrile reacts with phenyl magnesium bromide in presence of dry ether to give an imine complex which on acid hydrolysis gives a benzophenone. During reaction bcnzonitrile and phenyl magnesium bromide should be aken in equimolecular proportion.
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