Question
How do halogens react with other solvents and with hydrocarbons?

Answer

 
  • Halogens are soluble in various organic solvents such as chloroform, carbon disulphide and carbon tetrachloride
  • All halogens react with hydrocarbons and form mono or multisubstituted compounds.
  • The reactivity decreases down the group from fluorine to iodine.
    $\begin{aligned} & CH _4+2 F _2 \rightarrow C +4 HF
    \\ & C +2 F _2 \rightarrow CF _4
    \\ & CH _4+ Cl _2 \rightarrow CCl _4+4 HCl \end{aligned}$

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