Question
How does acetone reacts with HCN and NaHSO3?

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  1. Draw the geometrical isomers of complex [Pt(NH3)2Cl2].
  2. On the basis of crystal field theory, write the electronic configuration for d4 ion if $\Delta$0< P.
  3. Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].

(At. no. of Ni = 28)

How would you account for the following? 
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  2. The metallic radii of the third (5d) series of transition metals are virtually the same as those of the corresponding group members of the second (4d) series.
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A + 2B → 3C + 2D. The rate of disappearance of B is 1 × 10-2 mol L-1 s -1. What will be:
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  2. Rate of change in concentration of A and C?
  1. Calculate $\Delta$rGfor the reaction:

Mg (s) + Cu2+ (aq) $\rightarrow$ Mg2+ (aq) + Cu (s)
Given: Eocell = + 2.71 V, 1 F = 96500 C mol–1

  1. Name the type of cell which was used in Apollo space programme for providing electrical power.
Predict, giving reasons, the order of basicity of the following compounds in (i) gaseous phase and (ii) in aqueous solutions (CH3)3N, (CH3)2NH, CH3NH2, NH3.
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Explain the following in one or two sentences:
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The electrical resistance of a column of 0.05 M KOH solution of diameter 1 cm and length 45·5 cm is 4.55 $\times$ 103 ohm. Calculate its molar conductivity.
Give reasons:
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  2. Iron has higher enthalpy of atomization than that of copper.
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List various types of isomerism possible for coordination compounds, giving an example of each.