Question
How does colour appear in coordination compounds? Its explanation is based on crystal field theory.

Answer

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Explain the terms primary and secondary structure of proteins. What is the difference between α-helix and β-pleated sheet structure of proteins?
  1. Answer the following questions briefly:
  1. What are reducing sugars?
  2. What is meant by denaturation of a protein?
  3. How is oxygen replenished in our atmosphere?
  1. Define enzymes.
Graphically explain the effect of temperature on the rate constant of reaction. How can this temperature effect on rate constant be represented quantitatively?
Explain the open chain structure of glucose.
All energetically effective collisions do not result in a chemical change. Explain with the help of an example.
Attempt any five of the following:
(a) Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids. What is their relative configuration?
(b) What are the three components of nucleic acids?
(c) Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?
(d) Is nucleotide and nucleoside the same? What are their roles?
(e) Why cannot vitamin C be stored in our body?
(f) During curdling of milk, what happens to sugar present in it?
(g) Account for the following:
a. There are 5-OH groups in glucose.
b. Glucose is a reducing sugar
Explain in detail the changing oxidation states of the elements of d group (transition elements) in the context of 3d series.
Answer the following question:
The graphical representation of vapour pressures of two component system as a function of composition is given alongside. By graphic inspection, answer the following questions:
  1. Are the A-B interactions weaker, stronger or of the same magnitude as A-A and B-B?
  2. Name the type of deviation shown by this system from Raoult’s law.
  3. Predict the sign of $\Delta_\text{mix}\text{H}$ for this system.
  4. Predict the sign of $\Delta_\text{mix}\text{H}$ for this system.
  5. Give an example of such a system.
  6. What type of azeotrope will this system form, if possible?

A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes $FeSO_{4}$ and $ZnSO_{4}$ until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y. (Molar mass: $Fe = 56 g mol^{-1}, Zn = 65.3 g mol^{-1}, 1 F = 96500 C mol^{-1}$)
(a) What type of protein is present in keratin?
(b) Write the reactions showing the presence of following in the open structure of glucose:
   i. an aldehyde group
  ii. a primary alcohol
(c) What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
(d) Amino acids show amphoteric behaviour. Why?
(e) What are a Amino Acids? Give examples.
(f) a. How can you explain the absence of an aldehyde group in the pentaacetate of D-glucose?
    b. Name the bases present in RNA. Which one of these is not present in DNA?
(g) Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?