Question
How is zinc extracted from its carbonate ore (calamine)? Explain with equations.

Answer

When calamine ore is heated strongly in the absence of air i.e. calcined, it decomposes to form zinc oxide and carbon dioxide.
$\text{ZnCO}_{3}\text{(s)}\xrightarrow[]{\ \ \ \ \ \ \text{Calcination}\ \ \ \ \ }\text{ZnO}\text{(s)}\ \ \ +\ \ \text{CO}\text{(g)}\\\\\text{Zinc carbonate}\ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Zinc oxide}\ \ \ \ \ \text{Carbon oxide}\ \ \ \ \ \ \ \ \ \\\text{(Calmineore)}\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ $
Then zinc oxide is heated with carbon and zinc metal is produced.
$\text{ZnO}\text{(s)}\ \ \ \ +\ \ \text{C}\text{(s)}\ \ \ \xrightarrow{\ \ \ \ }\ \ \ \text{Zn}\text{(s)}\ \ \ +\ \ \ \text{CO}\text{(g)}\\ \text{Zinc oxide}\ \ \ \text{Carbon}\ \ \ \ \ \text{Zinc metal}\ \ \ \text{carbon monoxide}$

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