MCQ
Identify the coordination complexes in which the central metal ion has $d ^4$ configuration.
(A) $\left[ FeO _4\right]^{2-}$
(B) $\left[ Mn ( CN )_6\right]^{3-}$
(C) $\left[ Fe ( CN )_6\right]^{3-}$
(D)
Image
(E) $\left[ NiF _6\right]^{2-}$
Choose the correct answer from the options given below :
  • A
    (C) and (E) only
  • B
    (B), (C) and (D) only
  • (B) and (D) only
  • D
    (A), (B) and (E) only

Answer

Correct option: C.
(B) and (D) only
(C)
$\begin{array}{l} Fe ^{+6}=[ Ar ] 3 d^2 \\ Mn ^{+3}=[ Ar ] 3 d^4 \\ Fe ^{+3}=[ Ar ] 3 d^5 \\ Cr ^{+2}=[ Ar ] 3 d^4 \\ Ni ^{+4}=[ Ar ] 3 d^6\end{array}$

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