MCQ
In an irreversible process taking place at constant $T$ and $P$ and in which only pressure-volume work is being done, the change in Gibbs free energy $(dG)$ and change in entropy $(dS)$, satisfy the criteria
  • A
    ${(dS)_{V,\,E}} < 0,\,{(dG)_{T,\,P}} < 0$
  • ${(dS)_{V,\,E}} > 0,\,{(dG)_{T,\,P}} < 0$
  • C
    ${(dS)_{V,\,E}} = 0,\,{(dG)_{T,\,P}} = 0$
  • D
    ${(dS)_{V,\,E}} = 0,\,{(dG)_{T,\,P}} > 0$

Answer

Correct option: B.
${(dS)_{V,\,E}} > 0,\,{(dG)_{T,\,P}} < 0$
(b)${(dS)_{V,E}} > 0,{(dG)_{T,P}} < 0$.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

The stepwise formation of $\left[ Cu \left( NH _{3}\right)_{4}\right]^{2+}$ is given below

$Cu ^{2+}+ NH _{3} \stackrel{ K _{1}}{\rightleftharpoons}\left[ Cu \left( NH _{3}\right)\right]^{2+}$

$\left[ Cu \left( NH _{3}\right)\right]^{2+}+ NH _{3} \stackrel{ K _{2}}{\rightleftharpoons}\left[ Cu \left( NH _{3}\right)_{2}\right]^{2+}$

$\left[ Cu \left( NH _{3}\right)_{2}\right]^{2+}+ NH _{3} \stackrel{ K _{3}}{\rightleftharpoons}\left[ Cu \left( NH _{3}\right)_{3}\right]^{2+}$

$\left[ Cu \left( NH _{3}\right)_{3}\right]^{2+}+ NH _{3} \stackrel{ K _{4}}{\rightleftharpoons}\left[ Cu \left( NH _{3}\right)_{4}\right]^{2+}$

The value of stability constants $K _{1}, K _{2}, K _{3}$ and $K _{4}$ are $10^{4}, 1.58 \times 10^{3}, 5 \times 10^{2}$ and $10^{2}$ respectively. The overall equilibrium constants for dissociation of $\left[ Cu \left( NH _{3}\right)_{4}\right]^{2+}$ is $x \times 10^{-12}$ The value of $x$ is ...............

(Rounded off to the nearest integer)

A group of acidic oxide is
Which of the order for ionization energy is correct?
Consider the following reaction

(image) $\frac{{{H_2}}}{{pd - BaS{O_4}}}\,'A'$

The product $'A'$ is

Which of the following molecules is expected to rotate the plane of plane-polarised light ?
The hybridization of $Ag$ in the linear complex ${\left[ {Ag\,{{\left( {N{H_3}} \right)}_2}} \right]^ + }$ is
Which of the following compound is coloured ?
A mixture of one mole each of $H _{2}, He$ and $O _{2}$ each are enclosed in a cylinder of volume $V$ at temperature $T.$ If the partial pressure of $H _{2}$ is $2$ a$tm,$ the total pressure of the gases in the cylinder is$.......atm$
The arenium ion which is not involved in the bromination of Aniline is .
Image