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$\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{aq}),(1 \mathrm{M}) \| \mathrm{Fe}^{3+}(\mathrm{aq}), \mathrm{Fe}^{2+}(\mathrm{aq})\right| \mathrm{Pt}(\mathrm{s})$
The fraction of total iron present as $\mathrm{Fe}^{3+}$ ion at the cell potential of $1.500\, \mathrm{~V}$ is $\mathrm{X} \times 10^{-2}$. The value of $x$ is $.....$ (Nearest integer).
$\left(\right.$ Given $\left.E_{\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}}^{0}=0.77\, \mathrm{~V}, \mathrm{E}_{\mathrm{Zn}^{2+} / \mathrm{Zn}}^{0}=-0.76 \,\mathrm{~V}\right)$
$N{O_2} + {F_2}\xrightarrow{{slow}}N{O_2}F + F$
$N{O_2} + F\xrightarrow{{fast}}N{O_2}F$
Thus rate expression of the above reaction can be written as