MCQ
In the reaction, ${H_2} + {I_2}$ $\rightleftharpoons$ $2HI$. In a $2$ litre flask $0.4$ moles of each ${H_2}$ and ${I_2}$ are taken. At equilibrium $0.5$ moles of $HI$ are formed. What will be the value of equilibrium constant, ${K_c}$
  • A
    $20.2$
  • B
    $25.4$
  • C
    $0.284$
  • $11.1$

Answer

Correct option: D.
$11.1$
(d) $\mathop {\mathop {{H_2}}\limits_{0.4} }\limits_{0.4 - 0.25\; = \;0.15} $$ + $ $\mathop {\mathop {{I_2}}\limits_{0.4} }\limits_{0.4 - 0.25\; = \;0.15/2} $ $ \rightleftharpoons $ $\mathop {\mathop {2HI\,\,\,\,}\limits_{0.50\,\,\,\,} }\limits_{0.50/2} $

${K_c} = \frac{{{{[HI]}^2}}}{{[{H_2}][{I_2}]}} = \frac{{{{\left[ {\frac{{0.5}}{2}} \right]}^2}}}{{\left[ {\frac{{0.15}}{2}} \right]\,\left[ {\frac{{0.15}}{2}} \right]}}$$ = \frac{{0.5 \times 0.5}}{{0.15 \times 0.15}} = 11.11$

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