$\left(\mathrm{CH}_{3}\right)_{2} \bar {N}H>\mathrm{CH}_{3} \bar {N}H_{2}>$$\left(CH_{3}\right)_{3} \bar {N}>\mathrm{C}_{6}\ mathrm{H}_{5} \bar {N} \mathrm{H}_{2}$
As we know $\mathrm{pk}_{\mathrm{b}}=-\log \mathrm{K}_{\mathrm{b}}$
So $ (CH_3) _{2}$ $NH$ will have smallest $pK_{b}$ value. In the case of phenylamine, $N$ is attached to $s p^{2}$ hybridised carbon, hence it has highest $p K_{b}$ and least basic strength.
image$\xrightarrow{{A{c_2}O}}A\mathop {\xrightarrow{{B{r_2}}}}\limits_{C{H_3}COOH} B\mathop {\xrightarrow{{{H_2}O}}}\limits_{{H^ + }} C$ 


$CH_3 (CH_2)_8CH_2Br \xrightarrow[benzene]{KCN} CH_3 (CH_2)_8CH_2CN$
ઉપર ની હોફમેન બ્રોમાઈડ પ્રકિયા માં વપરાયેલા $NaOH $ ના મોલ ની સંખ્યા કેટલી હશે ?
