\({t_{99.9\% }} = \frac{{2.303 \times 45}}{{0.693}}\log {10^3} = 448\,\,\min \approx 7.5\,\,hrs\)
$2 \mathrm{HI}_{(\mathrm{g})} \rightarrow \mathrm{H}_{2(\mathrm{~g})}+\mathrm{I}_{2(\mathrm{~g})}$
પ્રક્રિયાનો ક્રમ................ છે.
$1$ | $2$ | $3$ | |
$\mathrm{HI}\left(\mathrm{mol} \mathrm{L}^{-1}\right)$ | $0.005$ | $0.01$ | $0.02$ |
Rate $\left(\mathrm{mol} \mathrm{L}^{-1} \mathrm{~s}-1\right)$ | $7.5 \times 10^{-4}$ | $3.0 \times 10^{-3}$ | $1.2 \times 10^{-2}$ |
$-\frac{d[{{N}_{2}}{{O}_{5}}]}{dt}={{K}_{1}}[{{N}_{2}}{{O}_{5}}]$ ,
$\frac{d[N{{O}_{2}}]}{dt}={{k}_{2}}[{{N}_{2}}{{O}_{5}}]$ ,
$\frac{d[{{O}_{2}}]}{dt}={{K}_{3}}[{{N}_{2}}{{O}_{5}}]$
તો $K_1$, $K_2$ અને $K_3 $ વચ્ચેનો સંબંધ શું થાય?