Permanganate \(\Rightarrow MnO _{4}^{-}\)
\(2 \times 2 P _{\pi}-3 d _{\pi}\)
\(1 \times 2 P _{\pi}-4 P _{\pi}\)
\((2)\) \(MnO _{4}^{2-} \Rightarrow\) green
\(MnO _{\stackrel -4} \Rightarrow\) purple/violet
\((3)\) Manganate contains \(1\) unpaired electron hence it is paramagnetic
where as permanganetic contains no unpaired electrons hence it is diamagnetic.
\((4)\) Both have d's hybridisation hence both have tetrahedral geometry.
$2 Cu ^{2+}+4 X ^{-} \rightarrow Cu _2 X _2( s )+ X _2$