કૉલમ$-I$ | કૉલમ$-II$ |
$(a)\;Co^{+3}$ | $(i)\;\sqrt{8}\; B.M.$ |
$(b)\;Cr^{+3}$ | $(ii)\;\sqrt{35}\; B.M.$ |
$(c)\;Fe^{+3}$ | $(iii)\;\sqrt{3}\; B.M.$ |
$(d)\;Ni^{+2}$ | $(iv)\;\sqrt{24}\; B.M.$ |
$(v)\;\sqrt{15}\; B.M.$ |
$(a)\quad (b)\quad (c)\quad (d)$
\(\mathrm{Co}^{3+} \rightarrow 1 \mathrm{s}^{2} 2 \mathrm{s}^{2} 2 \mathrm{p}^{6} 3 \mathrm{s}^{2} 3 \mathrm{p}^{6} 4 \mathrm{s}^{0} 3 \mathrm{d}^{6}\)
\(n=4\)
\(\mu=\sqrt{4(4+2)}=\sqrt{24} \mathrm{B} \cdot \mathrm{M}\)
\(\mathrm{Cr}^{+3} \rightarrow 1 \mathrm{s}^{2} 2 \mathrm{s}^{2} 2 \mathrm{p}^{6} 3 \mathrm{s}^{2} 3 \mathrm{p}^{6} 4 \mathrm{s}^{0} 3 \mathrm{d}^{3}\)
\(n=3\)
\(\mu=\sqrt{3(3+2)}=\sqrt{15} \mathrm{B} \cdot \mathrm{M}\)
\(\mathrm{Fe}^{3+} \rightarrow 1 \mathrm{s}^{2} 2 \mathrm{s}^{2} 2 \mathrm{p}^{6} 3 \mathrm{s}^{2} 3 \mathrm{p}^{6} 4 \mathrm{s}^{0} 3 \mathrm{d}^{5}\)
\(n=5\)
\(\mu=\sqrt{5(5+2)}=\sqrt{35} \mathrm{B} . \mathrm{M}\)
\(\mathrm{N}_{1}^{+2} \rightarrow 1 \mathrm{s}^{2} 2 \mathrm{s}^{2} 2 \mathrm{p}^{6} 3 \mathrm{s}^{2} 3 \mathrm{p}^{6} 4 \mathrm{s}^{0} 3 \mathrm{d}^{8}\)
\(n=2\)
\(\mu=\sqrt{2(2+2)}=\sqrt{8} \mathrm{B} \cdot \mathrm{M}\)
,$[M \,(AB)\, (CD) \,ef]^{n\,±}$ (જ્યાં $AB,\,CD-$ અસમમિતીય દ્વિદંતીય લિગાન્ડ્, $e$, $f-$ એકદંતીય લિગાન્ડ્)
$\left[\mathrm{V}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$
[ આપેલ પરમાણુ ક્રમાંક : $\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Fe}=26, \mathrm{Ni}=28 \mathrm{Cu}=29$ ]
(પ.ક્ર. : $Fe=26, Co= 27, Ni =28, Pt= 78$)