MCQ
Most stable carbonium ion is
- A${\mathop C\limits^ + _2}{H_5}$
- B${(C{H_3})_3}\mathop C\limits^ + $
- ✓${({C_6}{H_5})_3}\mathop C\limits^ + $
- D${C_6}{H_5}\mathop C\limits^ + {H_2}$
The ion $C{H_3} - \mathop {\mathop {{C^ + }}\limits_{|\;\;}^{|\;\;} \;\;}\limits_{C{H_3}}^{C{H_3}} $ is stabilised by hyperconjugation, a second order resonance.
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$\,\begin{array}{*{20}{c}}
{\,C{H_3} - \,CH - \,CH = C{H_2}\,\xrightarrow{{B{r_2}/aq.NaCl}}} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$