નીચે આપેલા એમિનો એસિડોના જલીય દ્રાવણ માટે $pKa$ નો ચઢતો ક્રમ શોધો ?
$Gly, Asp, Lys, Arg$
JEE MAIN 2019, Diffcult
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c
\(\underset{\begin{smallmatrix}
*Ly\sin e \\
(pl\,\,Value\,=\,9.8)
\end{smallmatrix}}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,\,\,\,CO{{O}^{-}} \\
|\,\,\, \\
{{H}_{3}}\bar{N}-C-H\,\,\,\,\,\,\,\,\, \\
\,\,|\,\,\,\,\, \\
\end{matrix} \\
\,\,\,C{{H}_{2}} \\
\,\,\,|\,\,\,\,\,\, \\
\begin{matrix}
\,\,\,C{{H}_{2}} \\
\,\,\,\,|\,\,\,\,\,\, \\
\,\,\,\,C{{H}_{2}} \\
\begin{matrix}
\,\,\,\,\,\,|\,\,\,\,\,\,\, \\
\,\,\,\,\,C{{H}_{2}} \\
\,\,\,\,|\,\,\,\,\, \\
\,\,\,{}^{+}N{{H}_{3}} \\
\end{matrix} \\
\end{matrix} \\
\end{matrix}}}\,\) \(\underset{\begin{smallmatrix}
*Arginine \\
(pl\,\,Value\,=\,10.8)
\end{smallmatrix}}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,\,\,\,CO{{O}^{-}} \\
|\,\,\, \\
{{H}_{3}}\overset{+}{\mathop{N}}\,-C-H\,\,\,\,\,\,\,\,\, \\
\,\,|\,\,\,\,\, \\
\end{matrix} \\
\,\,\,C{{H}_{2}} \\
\,\,\,|\,\,\,\,\,\, \\
\begin{matrix}
\,\,\,C{{H}_{2}} \\
\,\,\,\,|\,\,\,\,\,\, \\
\,\,\,\,C{{H}_{2}} \\
\begin{matrix}
\,\,\,\,\,\,|\,\,\,\,\,\,\, \\
\,\,\,\,\,NH \\
\,\,\,\,|\,\,\,\,\, \\
\begin{align}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C=\overset{+}{\mathop{N}}\,{{H}_{2}} \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{matrix}
|\,\,\,\,\,\,\,\,\,\, \\
\,\,\,\,N{{H}_{2}}\,\,\,\,\, \\
\end{matrix} \\
\end{align} \\
\end{matrix} \\
\end{matrix} \\
\end{matrix}}}\,\) \(\underset{\begin{smallmatrix}
\,\,\,\,\,\,\,\,\,Aspartate \\
(pl\,\,value\,\,=\,3.0)
\end{smallmatrix}}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CO{{O}^{-}} \\
\,\,\,\,\,\,| \\
{{H}_{3}}\overset{+}{\mathop{N}}\,-C-H \\
\,\,\,\,\,\,| \\
\end{matrix} \\
\,\,\,\,\,\,\,\,\,\,C{{H}_{2}} \\
\,\,\,\,\,| \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CO{{O}^{-}} \\
\end{matrix}}}\,\) \(\underset{\begin{smallmatrix}
\,\,\,\,\,\,\,\,\,\,\,Glycine \\
(pl\,\,\,Value\,\,=\,\,6.0)
\end{smallmatrix}}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,\,\,\begin{matrix}
\,\,\,\,\,CO{{O}^{-}} \\
|\,\,\,\, \\
\end{matrix} \\
{{H}_{3}}\overset{+}{\mathop{N}}\,-C-H \\
\,\,\,\,\,\,| \\
\,\,\,\,\,\,\,H \\
\end{matrix}}}\,\)
\(\underset{\begin{smallmatrix}
*Ly\sin e \\
(pl\,\,Value\,=\,9.8)
\end{smallmatrix}}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,\,\,\,CO{{O}^{-}} \\
|\,\,\, \\
{{H}_{3}}\bar{N}-C-H\,\,\,\,\,\,\,\,\, \\
\,\,|\,\,\,\,\, \\
\end{matrix} \\
\,\,\,C{{H}_{2}} \\
\,\,\,|\,\,\,\,\,\, \\
\begin{matrix}
\,\,\,C{{H}_{2}} \\
\,\,\,\,|\,\,\,\,\,\, \\
\,\,\,\,C{{H}_{2}} \\
\begin{matrix}
\,\,\,\,\,\,|\,\,\,\,\,\,\, \\
\,\,\,\,\,C{{H}_{2}} \\
\,\,\,\,|\,\,\,\,\, \\
\,\,\,{}^{+}N{{H}_{3}} \\
\end{matrix} \\
\end{matrix} \\
\end{matrix}}}\,\) \(\underset{\begin{smallmatrix}
*Arginine \\
(pl\,\,Value\,=\,10.8)
\end{smallmatrix}}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,\,\,\,CO{{O}^{-}} \\
|\,\,\, \\
{{H}_{3}}\overset{+}{\mathop{N}}\,-C-H\,\,\,\,\,\,\,\,\, \\
\,\,|\,\,\,\,\, \\
\end{matrix} \\
\,\,\,C{{H}_{2}} \\
\,\,\,|\,\,\,\,\,\, \\
\begin{matrix}
\,\,\,C{{H}_{2}} \\
\,\,\,\,|\,\,\,\,\,\, \\
\,\,\,\,C{{H}_{2}} \\
\begin{matrix}
\,\,\,\,\,\,|\,\,\,\,\,\,\, \\
\,\,\,\,\,NH \\
\,\,\,\,|\,\,\,\,\, \\
\begin{align}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C=\overset{+}{\mathop{N}}\,{{H}_{2}} \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{matrix}
|\,\,\,\,\,\,\,\,\,\, \\
\,\,\,\,N{{H}_{2}}\,\,\,\,\, \\
\end{matrix} \\
\end{align} \\
\end{matrix} \\
\end{matrix} \\
\end{matrix}}}\,\) \(\underset{\begin{smallmatrix}
\,\,\,\,\,\,\,\,\,Aspartate \\
(pl\,\,value\,\,=\,3.0)
\end{smallmatrix}}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CO{{O}^{-}} \\
\,\,\,\,\,\,| \\
{{H}_{3}}\overset{+}{\mathop{N}}\,-C-H \\
\,\,\,\,\,\,| \\
\end{matrix} \\
\,\,\,\,\,\,\,\,\,\,C{{H}_{2}} \\
\,\,\,\,\,| \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CO{{O}^{-}} \\
\end{matrix}}}\,\) \(\underset{\begin{smallmatrix}
\,\,\,\,\,\,\,\,\,\,\,Glycine \\
(pl\,\,\,Value\,\,=\,\,6.0)
\end{smallmatrix}}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,\,\,\begin{matrix}
\,\,\,\,\,CO{{O}^{-}} \\
|\,\,\,\, \\
\end{matrix} \\
{{H}_{3}}\overset{+}{\mathop{N}}\,-C-H \\
\,\,\,\,\,\,| \\
\,\,\,\,\,\,\,H \\
\end{matrix}}}\,\)
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