\((1)\) \(C r^{3+} \rightarrow 3 d^1 4 s^2\) no. of unpaired \(e^{-}=1\)
\((2)\) \(M n^{3+} \rightarrow 3 d^3 4 s^2\) no. of unpaired \(e^{-}=1\)
\((3)\) \(F e^{3+} \rightarrow 3 d^3 4 s^2 \quad\) no. of unpaired \(e^{-}=1\)
\((4)\) \(Co ^{3+} \rightarrow 3 d^6 4 s^2\) no. of unpaired \(e^{-}=0\)
So \(C o\) in \(\left[\operatorname{Co}(C N)_6\right]^{3-}\) is having less number of unpaired electrons
comparatively i.e 0 . So it is a diamagnetic compound means less paramagnetic comparatively.
$5 {Fe}^{2+}+{MnO}_{4}^{-}+8 {H}^{+} \rightarrow {Mn}^{2+}+4 {H}_{2} {O}+5 {Fe}^{3+}$
જ્યા, $gly =$ ગ્લાયસીન, $en =$ ઇથીલીન ડાયએમાઇન ,
$bpy =$ બાયપિરિડીલ મોઇટીસ
(પરમાણુક્રમાંક : $Ti = 22,V = 23, Fe = 26, C = 27$)