નીચેની પ્રક્રિયા શ્રેણીમાં સંયોજન $I$ શુ હશે ?

$\mathop I\limits_{({C_3}{H_6}C{l_2})} \xrightarrow{{KOH(aq)}}II\xrightarrow[{(ii){H_2}O/{H^ + }}]{{(i)C{H_3}MgBr}}III\xrightarrow{{Anhy.ZnC{l_2} + Conc.HCl}}$ તરત જ terbidity મળે છે

Question

નીચેની પ્રક્રિયા શ્રેણીમાં સંયોજન $I$ શુ હશે ?

$\mathop I\limits_{({C_3}{H_6}C{l_2})} \xrightarrow{{KOH(aq)}}II\xrightarrow[{(ii){H_2}O/{H^ + }}]{{(i)C{H_3}MgBr}}III\xrightarrow{{Anhy.ZnC{l_2} + Conc.HCl}}$ તરત જ terbidity મળે છે

A$\begin{array}{*{20}{c}}
{C{H_2} - CH - C{H_3}} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{Cl\,\,\,\,\,\,\,\,\,\,\,\,\,Cl\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
B$\begin{array}{*{20}{c}}
{C{H_2} - C{H_2} - C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,Cl\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,Cl\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
C$\begin{array}{*{20}{c}}
{CH - CH - C{H_2} - C{H_3}} \\
{\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{Cl\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
D$\begin{array}{*{20}{c}} {Cl} \\ | \\ {C{H_3} - C - C{H_3}} \\ | \\ {Cl} \end{array}$

JEE MAIN 2017, Advanced

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Solution

d
$\underset{(I)}{\mathop{\underset{({{C}_{3}}{{H}_{6}}C{{l}_{2}})}{\mathop{\begin{matrix}
\begin{matrix}
\,\,Cl \\
| \\
\end{matrix} \\
{{H}_{3}}C-C-C{{H}_{3}} \\
| \\
\,\,Cl \\
\end{matrix}}}\,}}\,$ $\xrightarrow[{(aq.)}]{{KOH}}$ $\mathop {\mathop {\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{\,\,\,\,OH} \\
|
\end{array}} \\
{C{H_3} - C - C{H_3}} \\
| \\
{\,\,\,\,OH}
\end{array}}\limits_{Unstable} }\limits \xrightarrow{{{H_2}O}}$ $\mathop {\begin{array}{*{20}{c}}
O \\
{||} \\
{C{H_3} - C - C{H_3}}
\end{array}}\limits_{(II)} $ $\xrightarrow[{(II)\,{H_2}O\,/\,{H^ \oplus }}]{{(I)\,C{H_3}MgBr}}$ ${\mathop {\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{\,\,\,\,OH} \\
|
\end{array}} \\
{C{H_3} - C - C{H_3}} \\
| \\
{\,\,\,\,C{H_3}}
\end{array}}\limits_{{3^0}\,alcohol} }$ $\xrightarrow[{Lucas\,\,\,Test}]{{Anhy.\,ZnC{l_3}\, + \,HCl}}$ Gives turbidity immediately

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