નીચેની પ્રક્રિયાની મુખ્ય નીપજ કઈ છે
${C_6}{H_5}C{H_2}CH(OH)CH{(C{H_3})_2}\xrightarrow{{conc.\,{H_2}S{O_4}}}\,?$
- A
- B
- C
- D
AIEEE 2010, Diffcult
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a
\(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - {\text{C}}{{\text{H}}_2} - {\text{CH}} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,\,C{H_3}}
\end{array}\) \(\xrightarrow{{{H^ + }}}\) \(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - {\text{C}}{{\text{H}}_2} - {\text{CH}} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\,_ + }O{H_2}\,\,\,\,\,C{H_3}}
\end{array}\) \(\to \) \(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - {\text{C}}{{\text{H}}_2} - \mathop {\text{C}}\limits^ + {\text{H}} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}\) \(\xrightarrow{{1,2\,\,{H^ + }\,\,shift}}\) \(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - \mathop {\text{C}}\limits^ + {\text{H}} - C{{\text{H}}_2} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}\) \(\xrightarrow{\Delta }\) \(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - C{\text{H}} = C{\text{H}} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}\)
\(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - {\text{C}}{{\text{H}}_2} - {\text{CH}} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,\,C{H_3}}
\end{array}\) \(\xrightarrow{{{H^ + }}}\) \(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - {\text{C}}{{\text{H}}_2} - {\text{CH}} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\,_ + }O{H_2}\,\,\,\,\,C{H_3}}
\end{array}\) \(\to \) \(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - {\text{C}}{{\text{H}}_2} - \mathop {\text{C}}\limits^ + {\text{H}} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}\) \(\xrightarrow{{1,2\,\,{H^ + }\,\,shift}}\) \(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - \mathop {\text{C}}\limits^ + {\text{H}} - C{{\text{H}}_2} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}\) \(\xrightarrow{\Delta }\) \(\begin{array}{*{20}{c}}
{{{\text{C}}_6}{{\text{H}}_5} - C{\text{H}} = C{\text{H}} - {\text{CH}} - {\text{C}}{{\text{H}}_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}\)
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