પ્રકિયા માં :

$\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - CH - C{H_2} - O - C{H_2} - C{H_3}}
\end{array}\,+ HI \, \xrightarrow{{Heated}}$

નીચેના સંયોજનોમાંથી કઇ રચના કરવામાં આવશે? ?

Question

પ્રકિયા માં :

$\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - CH - C{H_2} - O - C{H_2} - C{H_3}}
\end{array}\,+ HI \, \xrightarrow{{Heated}}$

નીચેના સંયોજનોમાંથી કઇ રચના કરવામાં આવશે? ?

AIPMT 2007, Medium

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Solution

c
When con. $HI$ or $HBr$ reacts with ether, the corresponding alcohol and iodide is formed. When there is a case of mixed ethers the halogen atom attaches to the smaller alkyl group, due to steric effect.

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