- A$BF_3 , BrF_3$
- B$ICl_2^{\ominus}, BeCl_2$
- C$BCl_3 , PCl_3$
- D$PCl_3,NCl_3$
$BrF_3$ $sp^3d$ Bent $'T'$ shape
$IC^{\ominus}_2$ $sp^3d$ Linear
$BeCl_2$ $sp$ Linear
$BCl_3$ $sp^2$ Trigonal planar
$PCl_3$ $sp^3$ Pyramidal
$NCl_3$ $sp^3$ Pyramidal
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(nearest integer)
[Given : Molar mass of $\mathrm{AB}_2=200 \mathrm{~g} \mathrm{~mol}^{-1} \cdot \mathrm{K}_{\mathrm{b}}$
(molal boiling point elevation const. of water)
$=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$, boiling point of water $=100^{\circ} \mathrm{C}$;
$\mathrm{AB}_2$ ionises as $\left.\mathrm{AB}_2 \rightarrow \mathrm{A}^{2+}+2 \mathrm{~B}^{-}\right]$