Question
State the general properties of ionic compounds.

Answer

  • The general (common) properties of ionic compounds are as follows :
  • $(1)$ Physical nature :
  • The ionic compounds are solids and hard because of the strong forces of attraction between the positive and negative ions.
  • These compounds are generally brittle and break into pieces when pressure is applied.
  • $(2)$ Melting and boiling points :
  • A considerable large amount of energy is required to break the strong inter-ionic attraction.
  • Hence, ionic compounds have high melting and boiling points.
  • For example,
Melting and boiling points of some ionic compounds
Ionic compound Melting point
$(K)$
Boiling point
$(K)$
$NaCl$ $1074$ $1686$
$LiCl$ $887$ $1600$
$CaCl_2$ $1045$ $1900$
$CaO$ $2850$ $3120$
$MgCl_2$ $981$ $1685$
  • $(3)$ Solubility :
  • Electrovalent (Ionic) compounds are generally soluble in polar solvent like water and insoluble in non-polar organic solvents such as kerosene, petrol, etc.
  • $(4)$ Conduction of electricity :
  • The conduction of electricity through a solution involves the movement of charged particles.
  • A solution of an ionic compound in water contains ions, which move to the opposite electrodes, when electricity is passed through the solution.
  • Ionic compounds in the solid state do not conduct electricity because the movement of ions in the solid is not possible due to their rigid structure.
  • But, ionic compounds conduct electricity in the molten state.
  • Since the electrostatic forces of attraction between the oppositely charged ions are overcome and free ions are obtained due to heat.
  • As a result, these ions move freely and conduct electricity.

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