Question
State why aluminium is extracted from its oxide by electrolysis while copper, lead, iron by reducing agents and mercury and silver by thermal decomposition.

Answer

Aluminium has a great affinity towards oxygen and so cannot be reduced by carbon or carbon monoxide. So it is extracted from its oxide by electrolysis.
Metals like copper, lead, and iron are placed in the middle of the activity series and re moderately reactive and their oxides can be reduced by carbon, CO and hydrogen. Mercury and silver are less reactive and are placed lower in the reactivity series. The oxides of these metals are reduced to metals by heating their oxides.

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