MCQ
The complex with a maximum number of stereoisomers is
- A$[PtCl_3(C_2H_4)]^-$
- B$[CuBr_2Cl_2]^{2-}$
- C$[Co(C_2O_4)_3]^{3-}$
- ✓$[Cr(NH_3)_2(en)_2]^{3+}$
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$Cl_2(aq) + H_2S(aq) \to S(s) + 2H^+(aq) + 2Cl^-(aq)$ rate law is $r = K[Cl_2][H_2S]$
then which of these mechanism is/are consistent with this rate law
$(A)\, H_2S \rightleftharpoons H^+ + HS^-$ (fast)
$Cl_2 + HS^-\to 2Cl^-+ H^+ + S$ (slow)
$(B)\, Cl_2 + H_2S \to H^+ + Cl^-+ Cl^+ + HS^-$ (slow)
$Cl^+ + HS^-\to H^+ + Cl^-+ S$ (fast)
$1-$ Bromopropane is reacted with reagents in List $I$ to give product in List $II$
| List$I-$ Reagent | List$II-$Product |
| $A$ $KOH (\text { alc) }$ | $I$ Nitrile |
| $B$ $KCN \text { (alc) }$ | $II$ Ester |
| $C$ $AgNO _2$ | $III$ Alkene |
| $D$ $H _3 CCOOAg$ | $IV$ Nitroalkane |
