MCQ
The correct increasing order of stability of the complexes based on $\Delta_{0}$ value is :
(I) $\left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}$
(II) $\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{4-}$
(III) $\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4}$
(IV) $\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}$
  • A
    II $<$ III $<$ I $<$ IV
  • B
    IV $<$ III $<$ II $<$ I
  • I $<$ II $<$ IV $<$ III
  • D
    III $<$ II $<$ IV $<$ I

Answer

Correct option: C.
I $<$ II $<$ IV $<$ III
(C)
Sol.
(I) $\left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}$ $-1.6 \Delta_{\mathrm{o}}$
(II) $\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{4-}$ $-1.8 \Delta_{\mathrm{o}}$
(III) $\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-}$ $-2.4 \Delta_{\mathrm{o}}$
(IV) $\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}$ $-2.0 \Delta_{\mathrm{o}}$
I $<$ II $<$ IV $<$ III

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