MCQ
The correct $\text{IUPAC}$ name of $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]$ is:
  • Diamminedichloridoplatinum $(II).$
  • B
    Diamminedichloridoplatinum $(IV).$
  • C
    Diamminedichloridoplatinum $(0).$
  • D
    Dichloridodiammineplatinum $(IV).$

Answer

Correct option: A.
Diamminedichloridoplatinum $(II).$
The complex compound is $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]. NH_3$ is a neutral ligand and named as amine$. Cl$ is anion ligand and named as chloride. Di or tri is prefixed to represent the number. So the name of the compound is$-$ Diamminedichloridoplatinum $(II).$
$(II)$ represent the oxidation state of platinum.

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$(I)$ $\begin{array}{*{20}{c}}
  {{C_6}{H_5} - CH - Cl} \\ 
  {\,\,|} \\ 
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\end{array}\xrightarrow[{5\% \,\,water}]{{95\% \,\,\,acetone}}\begin{array}{*{20}{c}}
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  | \\ 
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$(II)$ $\begin{array}{*{20}{c}}
  {{C_6}{H_5} - CH - Cl} \\ 
  {\,\,|} \\ 
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\end{array}\xrightarrow[{10\% \,\,water}]{{90\% \,\,\,acetone}}\begin{array}{*{20}{c}}
  {{C_6}{H_5} - CH - OH} \\ 
  | \\ 
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$(III)$ $\begin{array}{*{20}{c}}
  {{C_6}{H_5} - CH - Cl} \\ 
  {\,\,|} \\ 
  {\,\,\,\,\,\,C{H_3}} 
\end{array}\xrightarrow[{20\% \,\,water}]{{80\% \,\,\,acetone}}\begin{array}{*{20}{c}}
  {{C_6}{H_5} - CH - OH} \\ 
  | \\ 
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$(IV)$ $\begin{array}{*{20}{c}}
  {{C_6}{H_5} - CH - Cl} \\ 
  {\,\,|} \\ 
  {\,\,\,\,\,\,C{H_3}} 
\end{array}\xrightarrow{{100\% \,water}}\begin{array}{*{20}{c}}
  {{C_6}{H_5} - CH - OH} \\ 
  | \\ 
  {\,\,\,\,\,\,C{H_3}} 
\end{array}$

Arrange these reactions in decreasing order of greater proportion of inverted product and select correct answer from the codes given below :