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$[ R =$ gas constant, $F =$ Faraday constant, $T =$ Temperature $]$
$(A)$ For the reaction, $M (s)+2 H ^{+}(a q) \rightarrow H _2(g)+ M ^{2+}(a q)$, if $\frac{ dE _{c o l l}}{ dT }=\frac{ R }{ F }$, then the entropy change of the reaction is $R$ (assume that entropy and internal energy changes are temperature independent).
$(B)$ The cell reaction, $Pt (s) \mid H _2(g, 1$ bar $)\left| H ^{+}(a q, 0.01 M ) \| H ^{+}(a q, 0.1 M )\right| H _2(g, 1 bar ) \mid Pt (s)$, is an entropy driven process.
$(C)$ For racemization of an optically active compound, $\Delta S >0$.
$(D)$ $\Delta S >0$, for $\left[ Ni \left( H _2 O \right)_6\right]^{2+}+3$ en $\rightarrow\left[ Ni ( en )_3\right]^{2+}+6 H _2 O$ (where en $=$ ethylenediamine).
If $\mathop H\limits^ \oplus $ ion concentration is doubled, electrode potential of the half cell will
$A$. The strength of anionic ligands can be explained by crystal field theory.
$B$. Valence bond theory does not give a quantitative interpretation of kinetic stability of coordination compounds.
$C$. The hybridization involved in formation of $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ complex is $\mathrm{dsp}^2$.
$D$. The number of possible isomer$(s)$ of cis- $\left[\mathrm{PtCl}_2(\text { en })_2\right]^{2+}$ is one
Choose the correct answer from the options given below:
| Bromine | $Na$ metal | Chromic acid | Lucas reagent | |
| Compound $X$ | decolourises | bubbles | Orange to Green | No reaction |
| Compound $Y$ | No reaction | No reaction | No reaction | No reaction |
Compound $X$ and $Y$ respectively are
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The structure of $L -(-)$-glucose is