- ✓$CaF_2 > CaCl_2 > CaBr_2$ Melting point
- B$CH_3F > CH_3Cl > CH_3Br$ Dipole moment
- C$np_{\pi } - np\pi < ns-ns > ns-np$ Extent of overlapping
- D$H_2 > H_2^+ = H_2^-$ Stability
According to Fajans rule, the larger the size of the anion, greater is the covalent character of the ionic bond.
As covalent character increases, melting point decreases, thus order of melting point is:
$CaF _2\,> \,CaCl _2\,>\, CaBr _2$
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(Given) $\Delta H^o_f (CaCO_3,s) = -1207 \, \frac{kJ}{mol}$
$\Delta H^o_f \,(CaO,s) = -635 \,kJ/mol$
$\Delta H^o_f \,(CO_2.g) = -394 \,kJ/mol$
$(A)$ Addition of an electron in $O_2$ decreases bond order
$(B)$ Addition of an electron in $O_2$ increases bond order
$(C)$ Removal of an electron from $O_2$ increases bond length
$(D)$ Removal of an electron from $O_2$ decreases bond length
$2Al{(s)}+6HCl{(aq)} \rightarrow 2Al^{^{3+}}{(aq)}+6Cl^-{(aq)} +3H_2{(g)}$
$4NH_3 + 5O_2 \to 4NO + 6H_2O$