MCQ
The correct order of $'S-O'$ bond length is
- A$SO^{2-}_3 > SO^{2-}_4 > SO_3 > SO_2$
- ✓$SO^{2-}_3 > SO^{2-}_4 > SO_2 > SO_3$
- C$SO^{2-}_4 > SO^{2-}_3 > SO_2 > SO_3$
- D$SO^{2-}_4 > SO^{2-}_3 > SO_3 > SO_2$

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$(A)$ The hypochlorite ion is the strongest conjugate base.
$(B)$ The molecular shape of only chlorate ion is influenced by the lone pair of electrons of $Cl$.
$(C)$ The hypochlorite and chlorate ions disproportionate to give rise to identical set of ions.
$(D)$ The hypochlorite ion oxidizes the sulfite ion.
(Given atomic member $\mathrm{V}=23, \mathrm{Mn}=25, \mathrm{Cr}=24$ )
Given that :
$F{e^{2 + }} + 2{e^ - } \to Fe;$ ${E^o}_{F{e^{2 + }}/Fe} = - 0.47\,V$
$F{e^{3 + }} + {e^ - } \to F{e^{2 + }};$ ${E^o}_{F{e^{3 + }}/F{e^{2 + }}} = + 0.77\,V$
| $[A] (mol\,L^{-1})$ | $[B] (mol\,L^{-1})$ | Initial Rate $(mol\, L^{-1}\,s^{-1} )$ |
| $0.05$ | $0.05$ | $0.045$ |
| $0.10$ | $0.05$ | $0.090$ |
| $0.20$ | $0.10$ | $0.72$ |
