MCQ
The enthalpy change $(\Delta H)$ for the reaction, $N_2(g) + 3H_2(g) \to 2NH_3(g)$ is $-92.38\, KJ$ at $298\, K$ . The internal energy change $\Delta U$ at $298\, K$ is ....$ KJ$
  • A
    $-92.38$
  • $-87.42$
  • C
    $-97.34$
  • D
    $-89.9$

Answer

Correct option: B.
$-87.42$
b
$N _{2}( g )+3 H _{2}( g ) \rightarrow 2 NH _{3}( g )$

$\Delta H=-92.38 kJ$ at $298 K$

$\Delta E=?$

$\Delta H=\Delta E+\Delta n R T$

$\Delta n=2-(3+1)$

$=-2-92.38 \times 10^{3}$

$=\Delta E+8.314 \times(-2) \times 298$

$\Delta E=-87424.8 J =-87.425 kJ$

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