MCQ
The formula of the complex hydridotrimethoxyborate $(III)$ ion is :
  • $[BH(OCH_3)_3]^{2-}$
  • B
    $[BH_2(OCH_3)_3]^{2-}$
  • C
    $[BH(OCH_3)_3]^-$
  • D
    $[BH(OCH_3)_3]^+$

Answer

Correct option: A.
$[BH(OCH_3)_3]^{2-}$
a
$\mathrm{Mn}^{2+}=\mathrm{d}^{5}=\mathrm{t}_{2 \mathrm{g}}^{3} \mathrm{e}_{\mathrm{g}}^{2} \Rightarrow \mathrm{CFSE}=0$

$\mathrm{Co}^{+3}=\mathrm{d}^{6}=\mathrm{t}_{2 \mathrm{g}}^{6}$

$\mathrm{Fe}^{3+}=\mathrm{d}^{5}=\mathrm{t}_{2 \mathrm{g}}^{5}$

$\mathrm{Ni}^{2+}=\mathrm{d}^{8}=\mathrm{t}_{2 \mathrm{g}}^{6} \mathrm{e}_{g}^{2}$

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