Question
The halides of transition elements become more covalent with increasing oxidation state of the metal.

Answer

As the oxidation state increases, size of the ion of transition element decreases. As per Fajan's rule, as the size of metal ion decreases, covalent character of the bond formed increases.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

Calculate the electrode potential of copper electrode dipped in 0.1M $CuSO_4$ solution at 298K. Given that $\text{E}^{\circ}_{\text{cu}^{2}+/\text{cu}}=0.34\text{V}.$
A compound formed by elements $A$ and $B$ has a cubic structure in which $A$ atoms are at the corners of the cube and $B$ atoms are at the face centres. Derive the formula of the compound.
Complete the following chemical equations:
  1. $\mathrm{Cr}_2 \mathrm{O}_7{ }^{2-}+6 \mathrm{Fe}^{2+}+14 \mathrm{H}^{+} \rightarrow$
  2. $2 \mathrm{CrO}_4^{2-}+2 \mathrm{H}^{+} \rightarrow$
  3. $2 \mathrm{MnO}_4^{-}+5 \mathrm{C}_2 \mathrm{O}_4{ }^{2-}+16 \mathrm{H}^{+} \rightarrow$
Calculate e.m.f of the following cell at 298 K :
$2 \mathrm{Cr}(\mathrm{~s})+3 \mathrm{Fe}^{2+}(0.1 \mathrm{M}) \rightarrow 2 \mathrm{Cr}^{3+}(0.01 \mathrm{M})+3 \mathrm{Fe}(\mathrm{~s})$
$\text { Given: } \mathrm{E}^{\circ}\left(\mathrm{Cr}^{3+} \mid \mathrm{Cr}\right)=-0.74 \mathrm{VE}^{\circ}\left(\mathrm{Fe}^{2+} \mid \mathrm{Fe}\right)=-0.44 \mathrm{~V}$
$\text{E}^\ominus$ V of Cu is + $0.34V$ while that of Zn is – $0.76V$. Explain.
Calculate emf of the following cell at $25^{\circ} \mathrm{C}$ :
$\mathrm{Fe}\left|\mathrm{Fe}^{2+}(0.001 \mathrm{M})\right|\left|\mathrm{H}^{+}(0.01 \mathrm{M})\right| \mathrm{H}_2(\mathrm{~g})(1 \text { bar }) \mid \mathrm{Pt}(\mathrm{~s})$
$\mathrm{E}^{\circ}\left(\mathrm{Fe}^{2+} \mid \mathrm{Fe}\right)=-0.44 \mathrm{VE} \mathrm{E}^{\circ}\left(\mathrm{H}^{+} \mid \mathrm{H}_2\right)=0.00 \mathrm{~V}$
Explain Halogenation, Nitration, Sulphonation and Friedel crafts reaction of chlorobenzene.
Indicate the steps in the preparation of:
$K_2Cr_2O_7$ from chromite ore.
In each of the following pairs of compounds, identify the compound which will undergo $S_N1$ reaction faster.
Image
What happens when,
  1. A freshly prepared precipitate of $Fe(OH)_3$ is shaken with a small amount of $FeCl_3$ solution?
  2. Persistent dialysis of a colloidal solution is carried out?
  3. An emulsion is centrifuged?