MCQ
The ${K_{SP}}$ of $AgI$ is $1.5 \times {10^{ - 16}}$. On mixing equal volumes of the following solutions, precipitation will occur only with
  • A
    ${10^{ - 7}}\,M\,A{g^ + }$ and ${10^{ - 19}}\,M\,{I^ - }$
  • ${10^{ - 8}}\,M\,A{g^ + }$and ${10^{ - 8}}\,M\,{I^ - }$
  • C
    ${10^{ - 16}}\,M\,A{g^ + }$ and ${10^{ - 16}}\,M\,{I^ - }$
  • D
    ${10^{ - 9}}\,M\,A{g^ + }$ and ${10^{ - 9}}\,M\,{I^ - }$

Answer

Correct option: B.
${10^{ - 8}}\,M\,A{g^ + }$and ${10^{ - 8}}\,M\,{I^ - }$
(b) ${K_{sp\,}}\,\,{\rm{of}}\,\,AgI = 1.5 \times {10^{ - 16}}$

${10^{ - 8}}\,\,M\,\,A{g^ + }\,\,{\rm{and}}\,\,{10^{ - 8}}\,\,M\,\,{I^ - }$

${\rm{Ionic}}\,\,{\rm{product}} = {10^{ - 16}}$

${K_{sp}} = {\rm{Ionic}}\,\,{\rm{product}}$

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