- A$[He]\, 2s^1$
- B$[Ne]\, 3s^2$
- ✓$[Xe]\, 6s^1$
- D$[Xe]\, 6s^2$
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$(i)$ $\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}-CH_2} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,|}
\end{array}} \\
{C{H_3} - {C^ + }} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}$
$(ii)$ $\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,|}
\end{array}} \\
{C{H_3} - {C^ + }} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{H}}
\end{array}$
$(iii)$ $\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,|}
\end{array}} \\
{C{H_3} - {C^ + }} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}$
$(iv)$ $Ph - CH ^{+}-\underline{ CH }_{3}$
The mass (in $\mathrm{mg}$ ) of $\mathrm{S}$ obtained is. . . . . . . [Use molar mass (in g mol ${ }^{-1}$ ) : $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{Br}=80$ ]
| Column $-I$ | Column $-II$ |
| $(i)$ $n-$ Butane $\to 2-$ methyl propane | $(A)$ Free redical substitution |
| $(ii)$ $C{H_4} + C{l_2} \xrightarrow{{hv}} C{H_3} + Cl$ | $(B)$ Wurtz reaction |
| $(iii)$ $R - COONa\xrightarrow{{soda - \lim e}}R - H$ | $(C)$ Isomerism |
| $(iv)$ $R - X + Na\xrightarrow{{{\text{E}}ther}}R - R$ | $(D)$ De-carboxylation |