$2, 4, 6−$trinitrophenol is picric acid. It is acidic in nature. The withdrawing nature of $\ce{NO_2}$ groups make the compound acidic.
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Compound $\ce{C_2H_6O}$ has two isomers $X$ and $Y.$ On reaction with $HI, X$ gives alkyl iodide and water while $Y$ gives alkyl iodide and alcohol.Compounds $X$ and $Y$ are respectively: