- A3p
- ✓3d
- C3s
- D3f
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$(I)$ $\begin{array}{*{20}{c}}
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{O - S - {C_6}{H_4} - C{H_3}} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}\,$ $(II)$ $\begin{array}{*{20}{c}} {O\,\,\,\,\,\,\,} \\ {||\,\,\,\,\,\,\,} \\ {O - S - {C_6}{H_5}} \\ {||\,\,\,\,\,\,\,} \\ {O\,\,\,\,\,\,\,} \end{array}\,$$(III)$ $N_3$ $(IV)$ $Br$
Statement $I$: $\mathrm{S}_8$ solid undergoes disproportionation reaction under alkaline conditions to form $\mathrm{S}^{2-}$ and $\mathrm{S}_2 \mathrm{O}_3{ }^{2-}$
Statement $II$: $\mathrm{ClO}_4^{-}$can undergodisproportionation reaction under acidic condition. In the light of the above statements, choose the most appropriate answer from the options given below :

$Cu ( s )+2 Ag ^{+}( aq ) \rightleftharpoons Cu ^{2+}( aq )+2 Ag ( s )$
The equilibrium constant for the reaction.$\frac{1}{2} Cu ^{2+}( aq )+ Ag ( s ) \rightleftharpoons \frac{1}{2} Cu ( s )+ Ag ^{+}( aq )$ is $x \times 10^{-8}$. The value of $x$ is (Nearest Integer)
