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$(a)$ $\begin{array}{*{20}{c}}
{C{H_3} - CH - Br} \\
{|\,\,} \\
{\,\,\,\,\,{C_2}{H_5}\,}
\end{array}$ $(b)$ $\begin{array}{*{20}{c}}
{\,\,Br\,} \\
{|\,} \\
{C{H_3} - C - C{H_3}} \\
{|\,} \\
{\,\,\,\,\,{C_2}{H_5}}
\end{array}$ $(c)$ $\begin{array}{*{20}{c}}
{{C_2}{H_5} - CH - C{H_2}Br} \\
{\,\,|\,\,\,\,\,\,\,\,\,\,\,} \\
{{C_2}{H_5}\,\,}
\end{array}$
$BrO_{3(aq)}^ - \, + \,5Br_{(aq)}^ - \, + \,6{H^ - }\, \to \,3B{r_{2(l)}}\, + \,3{H_2}{o_{(l)}}.$
The rate of appearance of bromine $(Br_2)$ is related to rate of disappearance of bromide ions as