MCQ
The reaction of $HBr$ with $\begin{array}{*{20}{c}}
  {\,\,\,\,\,C{H_3}} \\ 
  | \\ 
  {C{H_3} - C = C{H_2}} 
\end{array}$ in the presence of peroxide will give
  • A
    $\begin{array}{*{20}{c}}
      {C{H_3}CBrC{H_3}} \\ 
      {\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
      {\,\,C{H_3}\,\,\,} 
    \end{array}$
  • B
    $CH_3$ $CH_2$ $CH_2$ $CH_2$ $Br$
  • $\begin{array}{*{20}{c}}
      {\,\,C{H_{3\,\,\,\,\,\,\,}}} \\ 
      {|\,\,\,\,\,\,\,\,\,\,\,} \\ 
      {C{H_3}CHC{H_2}Br} 
    \end{array}$
  • D
    $\begin{array}{*{20}{c}}
      {\,\,\,\,\,\,\,\,\,\,\,C{H_3}} \\ 
      {\,\,\,\,\,|} \\ 
      {C{H_3}C{H_2}CHC{H_3}} 
    \end{array}$

Answer

Correct option: C.
$\begin{array}{*{20}{c}}
  {\,\,C{H_{3\,\,\,\,\,\,\,}}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {C{H_3}CHC{H_2}Br} 
\end{array}$
c
$\begin{array}{*{20}{c}}
  {C{H_3} - C = C{H_2}} \\ 
  {|\,\,\,} \\ 
  {\,\,C{H_3}} 
\end{array}$ $\mathop {\xrightarrow{{HBr/peroxide}}}\limits_{anti.\,Markownkoffs\,addtion} $ $\begin{array}{*{20}{c}}
  {C{H_3} - CHC{H_2} - Br} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {\,\,C{H_3}\,\,\,\,\,\,\,} 
\end{array}\,$

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