- A$HCl$
- B$H_2S$
- C$PH_3$
- ✓$SiH_4$
$H _2 S$ boiling point $216\, K$.
$HCl$ boiling point $188\, K$.
$PH _3$ boiling point $185\, K$
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$\mathrm{Cr}_2 \mathrm{O}_7{ }^{2-}+14 \mathrm{H}^{+}+6 \mathrm{e}^{-} \rightarrow 2 \mathrm{Cr}^{3+}+7 \mathrm{H}_2 \mathrm{O}, \mathrm{E}^{\circ}=1.33 \mathrm{~V}$
$\mathrm{Fe}^{3+}(\mathrm{aq})+3 \mathrm{e}^{-} \rightarrow \mathrm{Fe} \mathrm{E}^{\circ}=-0.04 \mathrm{~V}$
$\mathrm{Ni}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{Ni} \mathrm{E}^{\circ}=-0.25 \mathrm{~V}$
$\mathrm{Ag}^{+}(\mathrm{aq})+\mathrm{e}^{-} \rightarrow \mathrm{Ag} \mathrm{E}^{\circ}=0.80 \mathrm{~V}$
$\mathrm{Au}^{3+}(\mathrm{aq})+3 \mathrm{e}^{-} \rightarrow \mathrm{Au} \mathrm{E}^{\circ}=1.40 \mathrm{~V}$
Consider the given electrochemical reactions, The number of metal$(s)$ which will be oxidized be $\mathrm{Cr}_2 \mathrm{O}_7{ }^{2-}$, in aqueous solution is. . . . . .
$(a)$ They might be configurational isomers $(b)$ They might be diastereomers
$(c)$ They might be constitutional isomers $(d)$ They might be tautomers
$(e)$ They might be conformational isomers $(f)$ They might be enantiomers
$(g)$ They might be positional isomers

(Round off to the Nearest Integer).