Question
The two $\text{O}-\text{O}$ bond distances in ozone molecule are equal. Justify.

Answer

It is due to resonance.

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What are the oxidation number of the underlined elements in the following and how do you rationalise your results?
KI3
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  1. Which out of NH3 and NF3 has higher dipole moment and why?
Which of the following sets of orbitals are degenerate and why?
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Balance the following redox reactions by ion-electron method:

H2O2(aq) + Fe2+(aq) → Fe3+(aq) + H2O(l) (in acidic solution).

In a reaction
$A + B _2 \rightarrow AB _2$
Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
  1. List two main differences between orbit and orbital.
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(h = 6.626 × 10-34Js and mass of election = 9.11 × 10-31kg)

Explain the term 'standard molar free energy of formation’ of a compound. Calculate the equilibrium constant for the reaction:

$2\text{SO}_2(\text{g})+\text{O}_2(\text{g})\rightleftharpoons2\text{SO}_3(\text{g})$ at 25°C.

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What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

Identify the type of redox reaction taking place in the following.
  1. $3\stackrel{0\ \ \ \ \ \ \ \ \ \ \ \ }{\text{Mg(s)}}+\stackrel{0\ \ \ \ \ \ \ \ \ \ \ }{\text{N}_2\text{(g)}}\ \xrightarrow{\ \ \ \ \ \ \ \ \ \ }\ \stackrel{+2\ \ \ \ -3\ \ \ \ \ \ \ \ }{\text{Mg}_3\text{N}_2\text{(s)}}$
  2. $\stackrel{+5\ \ \ \ \ \ -2\ \ \ \ \ \ \ }{\text{V}_2\text{O}_5\text{(s)}}5\stackrel{0\ \ \ \ \ \ \ \ \ \ }{\text{Ca(s)}}\xrightarrow{\ \ \ \ \ \ \ }2\stackrel{0\ \ \ \ \ \ \ \ }{\text{V(s)}}+\text{5}\stackrel{+2\ \ -2\ \ \ \ \ \ \ \ \ \ }{\text{CaO(s)}}$
  3. $2\stackrel{+1\ +5\ -2\ \ \ \ \ \ \ \ \ \ \ \ }{\text{KClO}_3(\text{s})}\xrightarrow{\ \ \ \ \ \ \ }2\stackrel{+1\ \ -1\ \ \ \ \ \ \ \ \ \ }{\text{KCl(s)}}+3\stackrel{0\ \ \ \ \ \ \ \ \ \ }{\text{O}_2\text{(g)}}$
  4. $\stackrel{0}{\text{Ca}\text{(s)}}+2\stackrel{+1-2}{\text{H}_2\text{O}\text{l}}\ \xrightarrow{\ \ \ \ \ \ \ \ \ \ \ }\stackrel{+2\ \ -2+1\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ }{\text{Ca(OH)}_2(\text{aq})}+\stackrel{0}{\text{H}}_2\text{(g)}$
  5. $\stackrel{0\ \ \ \ \ \ \ \ \ \ \ }{\text{Br}_2(\text{l})}+\stackrel{-1\ \ \ \ \ \ \ \ \ \ \ \ }{2\text{I}^-(\text{aq})}\xrightarrow{\ \ \ \ \ \ \ \ \ \ }\stackrel{1-}{\text{2Br}^-}(\text{aq})+\stackrel{0\ \ \ \ \ \ \ \ \ \ }{\text{I}_2\text{(s)}}$