MCQ
The values of ${K_{{P_1}}}$ and ${K_{{P_2}}}$ for the reaction

$X \rightleftharpoons Y + Z -  -  -  -  -  - \left( 1 \right)$

$A \rightleftharpoons 2B -  -  -  -  -  - \left( 2 \right)$

are in ratio of $9 :1$. If degree of dissociation of $X$ and $A$ be equal, then total pressure at equilibrium $(1)$ and $(2)$ are in the ratio

  • $36 :1$
  • B
    $1 : 1$
  • C
    $3 : 1$
  • D
    $1 : 9$

Answer

Correct option: A.
$36 :1$
a
$\mathop X\limits_{1 - \alpha }  \rightleftharpoons \mathop Y\limits_\alpha   + \mathop Z\limits_\alpha  $

$P_{x}=\left(\frac{1-\alpha}{1+\alpha}\right) P_{1} \& P_{y}=\left(\frac{\alpha}{1-\alpha}\right) P_{1} \& P_{z}=\left(\frac{\alpha}{1+\alpha}\right) P_{1}$

$\mathrm{K}_{\mathrm{R}}=\frac{\mathrm{P}_{\mathrm{y}} \times \mathrm{P}_{\mathrm{z}}}{\mathrm{P}_{\mathrm{x}}}$

$\mathop {\mathop A\limits_1 }\limits_{1 - \alpha }  \rightleftharpoons \mathop {\mathop {2B}\limits_0 }\limits_{2\alpha } $

$P_{A}=\left(\frac{1-\alpha}{1+\alpha}\right) P_{2} \& P_{B}=\left(\frac{2 \alpha}{1+\alpha}\right) P_{2}$

$\mathrm{K}_{\mathrm{P}_{2}}=\frac{\mathrm{P}_{\mathrm{B}}^{2}}{\mathrm{P}_{\mathrm{A}}}$

$\frac{\mathrm{K}_{\mathrm{R}}}{\mathrm{K}_{\mathrm{p}_{2}}}=\frac{9}{1}$

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