- ADue to small size
- BDue to metallic nature
- ✓Due to unpaired $d -$ electrons
- DAll of these
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(image) $\xrightarrow{{NBS}}\,\,\xrightarrow[{ether}]{{Mg}}\,\xrightarrow[{2.{H^ + }}]{{1.C{O_2}}}\,X$
$Pt(s)|Cl_2(g)|Cl^-(aq)||Ag^+(aq)|Ag(s)$
$H{_2(g)} + 2ICl_{(g)} \to 2HCl_{(g)} + I_{2(g)}$
This reaction is of first order with respect to $H_{2(g)}$ and $ICl_{(g)}$ , following mechanisms were proposed
Mechanism $A$ :
$H{_2(g)} + 2ICl_{(g)} \to 2HCl_{(g)} + I_{2(g)}$
Mechanism $B$ :
$H_{2(g)} + ICl_{(g)} \to HCl_{(g)} + HI_{(g)}$ ; Slow
$HI_{(g)} + ICl_{(g)} \to HCl_{(g)} + I_{2(g)}$ ; Fast
Which of the above mechanism $(s)$ can be consistent with the given information about the reaction
$(I)$ $S_2O_4^{2-}$ $(II)$ $S_2O_5^{2-}$ $(III)$ $S_2O_6^{2-}$